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Organic reaction mechanisms 40 solved cases2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载

Organic reaction mechanisms 40 solved cases
  • Mar Gómez Gallego ; M. A. Sierra 著
  • 出版社： Springer
  • ISBN：3540003525
  • 出版时间：2004
  • 标注页数：292页
  • 文件大小：62MB
  • 文件页数：301页
  • 主题词：

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图书目录

Level 11

Case 1. A Surprise in the Synthesis of Guanacastepene A1

Case 2. Sulfenylation of Indole7

Case 3. Substrate Selective Reactions in the Presence of Lewis Acids13

Case 4. Diastereoselective Reductions of β-Ketoesters21

Case 5. Rearrangements from Tetrahydropyran Derivatives27

Case 6. Stereospecific Substitution Reactions of Epoxy Sulfides33

Case 7. NaBH4 Reduction of α，β-Unsaturated Chromium Carbene Complexes39

Case 8. Addition of Hydroxylamines to α，β-Unsaturated Esters47

Case 9. Solvolysis of Electron-Deficient Norbomyl Triflates55

Case 10 Nucleophile Versus Base Catalysis63

Case 11. The Hydrolysis ofp-Substituted Styrene Oxides69

Case 12. Elimination Reactions of Benzaldehyde O-Benzoyloximes79

Case 13. Oxygen Versus Sulfur Stabilization of Carbenium Ions87

Case 14. Cyclization of 2，3-Dibenzylidenesuccinates97

Case 15. Oxazoline N-Oxides as Dipoles in [3＋2] Cycloadditions101

Case 16. Light-Induced Cycloadditions of N-Phthaloyl α-Amino Acids107

Level 2113

Case 17. Change in Rate-Determining Step in an E 1 cB Mechanism：Aminolysis of Sulfamate Esters113

Case 18. Unusual Diels-Alder Reactivity of Acyclic 2-Azadienes119

Case 19. Chelate-Controlled Carbonyl Addition Reactions125

Case 20. Esterification of Carboxylic Acids with Dimethyl Carbonate and DBU131

Case 21. A Hammett Analysis in a Multistep Reaction：Rhodium（Ⅱ）-Catalyzed Decomposition of α-Diazo Esters139

Case 22. Tandem Cycloadditions with Nitronates145

Case 23. Hydrolysis of 2-Aminobenzoate Esters153

Case 24. Rearrangements of Cyclobutenones159

Case 25. Epoxi Ester-Orthoester Rearrangement163

Case 26. 2-Chloro-1，3，5-triazines as Activating Groups of Carboxylic Acids in the Formation of Peptide Bonds169

Case 27. Acid-Catalyzed Isomerization of Imines177

Case 28. A Dearomatizing Disrotatory Electrocyclic Ring Closure183

Case 29. Stereoselective Debromination of Vicinal Dibromides189

Case 30. Diels-Alder Reactions of N-Acyl-1，2，4，5-tetrazines197

Case 31. Stereoselective Synthesis of 2-Acylaziridines203

Level 3211

Case 32. The Baylis-Hillman Reaction211

Case 33. The Rate-Determining Step in the SNAr Reaction217

Case 34. Helicenophanes and their Racemization225

Case 35. Solvolysis of Vinyl Iodonium Salts231

Case 36. Vicarious Nucleophilic Substitution237

Case 37. Base-promoted HF Elimination from 4-Fluoro-4-（4′-nitrophenyl）butan-2-one243

Case 38. Substitution of β-Halostyrenes by MeS-251

Case 39. Periodinane-Mediated Cyclization of Anilides259

Case 40. Solvolysis of 8-Deltacyclyl Brosylates269

Subject Index277

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