超分子化学 合成受体的分子识别与组装2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载

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1．1 From molecular chemistry to supramolecular chemistry1

1．1 从分子化学到超分子化学1

第1章 超分子化学概述1

Chapter 1 Brief introduction of supramolecular chemistry1

1．2 Fundamental concept of molecular recognition2

1．2分子识别的基本概念2

1．3分子组装的基本概念3

1．3 Fundamental concept of molecular assembly3

References5

参考文献5

2．1 Synthesis of crown compounds6

2．1．1 Introduction6

第2章 冠状化合物为受体的分子识别与组装6

2．1冠状化合物的合成6

2．1．1概述6

Chapter 2 Molecular recognition and assembly with crown compounds as receptors6

2．1．2 Nomenclature of crown compounds7

2．1．2冠状化合物的命名7

2．1．3 Synthesis of crown compounds8

2．1．3冠状化合物的合成8

2．2．1概述38

2．2冠醚化合物的分子识别38

2．2 Molecular recognition of crown ethers38

2．2．1 Introduction38

2．2．2 Symmetric crown ethers40

2．2．2一般对称性冠醚40

2．2．3 Crown ethers of low symmetry48

2．2．3低对称性冠醚48

2．2．4 臂式冠醚57

2．2．4 Lariat ethers57

2．2．5双冠醚90

2．2．5 Bis(crown ether)s90

2．2．6 Cryptands104

2．2．6 穴醚104

2．2．7 其他类型冠醚114

2．2．7 Hybrid crown ethers114

2．3．1由单一分子形成的组装体123

2．3以冠醚为受体的分子组装123

2．3 Molecular assembly of crown ethers123

2．3．1 Assembly by single component123

2．3．2 Assembly by double components128

2．3．2由两种分子形成的组装体128

2．3．3 Assembly by multiple components132

2．3．3 由多种分子形成的组装体132

2．3．4索烃（Catenanes）137

2．3．4 Catenanes137

2．3．5 Pseudorotaxanes and rotaxanes143

2．3．5 轮烷（Rotaxanes）和准轮烷（Pseudorotaxanes）143

References150

参考文献150

Chapter 3 Molecular recognition and assembly with cyclodextrins as receptors166

3．1 Structural feature of cyclodextrin166

3．1．1 Historical background of cyclodextrins166

3．1．1环糊精研究的历史背景166

3．1 环糊精的基本结构特征166

第3章 以环糊精为受体的分子识别与组装166

3．1．2 Peparation of cyclodextrins167

3．1．2环糊精的制备167

3．1．3 Structure and physical properties of cyclodextrins168

3．1．3环糊精的结构和物理性质168

3．2 Synthetic strategy of cyclodextrin derivatives171

3．2 环糊精衍生物的合成方法171

3．2．1 Mono modification on the primary side172

3．2．1 6位单取代环糊精的制备172

3．2．2 2位和3位单取代环糊精的制备180

3．2．2 Mono modification on the secondary side180

3．2．3 Multiple substituted cyclodextrins187

3．2．3 多取代环糊精的制备187

3．3．1 Intermolecular forces analysis of the inclusion complexation by cyclodextrins191

3．3 Molecular recognition of cyclodextrins and their derivatives191

3．3 环糊精及其衍生物的分子识别研究191

3．3．1环糊精包结配位过程中的分子间力相关分析191

3．3．2天然环糊精的包结配位作用193

3．3．2 Inclusion complexation of native cyclodextrins193

3．3．3 Molecular recognition of positively charged cyclodextrins207

3．3．3 拥有电荷中心的简单修饰糊精的分子识别207

3．3．4 Molecular recognition of chromophoric cyclodextrins215

3．3．4 拥有生色基的简单修饰环糊精的分子识别215

3．3．5 Molecular recognition of bridged bis(cyclodextrin)s239

3．3．5 桥联环糊精的分子识别239

3．4 环糊精及其衍生物的模拟酶研究249

3．4 Cyclodextrins and their derivatives as enzyme models249

3．4．1水解酶的模拟250

3．4．1 Mimics of hydrolyse250

3．4．2 Mimics of transaminase255

3．4．2 转氨酶的模拟255

3．4．3 核糖核酸酶的模拟258

3．4．3 Mimics of ribonuclease258

3．4．4 氧化还原酶的模拟262

3．4．4 Mimics of oxido reductase262

3．4．5 其他类型的人工酶267

3．4．5 Other enzyme mimics267

3．5．1 Self-assembly of cyclodextrin derivatives with hydrophobic substituent in solution and solid state270

3．5 Molecular assembly with cyclodextrins as receptors270

3．5以环糊精为受体的分子组装270

3．5．1拥有疏水性取代基环糊精衍生物在溶液和固态中的自组270

3．5．2 Self-assembly with small molecules as bridge in solution and solid state273

3．5．2 通过小分子桥在水溶液和固态中的自组装273

3．5．3 分子索烃275

3．5．3 Catenanes275

3．5．4 Pseudorotaxanes and rotaxanes277

3．5．4 轮烷与准轮烷277

3．5．5 Mono layers and multiple layers286

3．5．5 单分子膜和多层膜286

3．5．6其他类型的环糊精组装体288

3．5．6 Other assembly of cyclodextrins288

References291

参考文献291

Chapter 4 Molecular recognition and assembly with calixarenes as receptors306

第4章 杯芳烃为受体的分子识别与组装306

4．1杯芳烃的合成与制备308

4．1．1一步合成法308

4．1 Synthesis and preparation of calixarenes308

4．1．1 One-pot procedures308

4．1．2多步合成法311

4．1．2 Stepwise synthesis311

4．1．3 Fragment condensation313

4．1．3片段缩合法313

4．1．4其他类型杯状化合物的合成317

4．1．4 Synthesis of other related macrocycles317

4．1．5 Derivation of calixarenes320

4．1．5 杯芳烃的衍生化320

4．2 Conformations of calixarenes328

4．2杯芳烃的构象328

4．3．1对中性分子的识别333

4．3．1 Neutral molecule recognition by calixarenes333

4．3 Molecular and ion recognition of calixarenes333

4．3杯芳烃的分子识别和离子识别333

4．3．2 对有机阳离子的识别338

4．3．2 Organic cation recognition by calixarenes338

4．3．3 对金属阳离子的识别340

4．3．3 Metal ion recognition by calixarenes340

4．3．4 Anion recognition by calixarenes351

4．3．4 对阴离子的识别351

4．4 Molecular catalysis and artificial enzyme with calixarenes as receptors356

4．4杯芳烃为受体的分子催化和模拟酶研究356

4．4．1相转移催化356

4．4．1 Phase transfer catalysis356

4．4．2 Mimic enzymes358

4．4．2模拟酶358

4．5以杯芳烃为受体的分子组装361

4．5 Moleculr assembly with calixarenes as receptors361

References372

参考文献372

Chapter 5 Molecular recognition and assembly with other macrocycles as receptors385

第5章 其他类型大环化合物为受体的分子识别与组装385

5．1 Cucurbituril385

5．1 葫芦脲385

5．1．1 Molecular recognition387

5．1．1分子识别387

5．1．2超分子催化393

5．1．2 Supramolecular catalysis393

5．1．3 Molecular assembly394

5．1．3分子组装394

5．2卟啉和酞菁400

5．2 Porphyrins and phthalocyanines400

5．2．1分子识别401

5．2．1 Molecular recognition401

5．2．2超分子催化420

5．2．2 Supramolecular catalysis420

5．2．3 Supramolecular self-assembly429

5．2．3超分子自组装429

5．3．1 Ion recognition439

5．3环肽439

5．3．1离子识别439

5．3 Cyclopeptides439

5．3．2环肽构筑的有机纳米管道443

5．3．2 Organo nanotube constructed by cyclopeptides443

References448

参考文献448

6．1大环化合物离子识别的热力学性质454

第6章 超分子体系中分子识别的热力学起源454

Chapter 6 Thermodynamic origin of molecular recognition in supramolecular system454

6．1 Thermodymamics of ion recognition by macrocycles454

6．1．1离子-配体络合作用的热力学参数455

6．1．1 Thermodynamic parameters for cation-ligand complexation455

6．1．2 焓熵补偿500

6．1．2 Enthalpy-entropy compensation500

6．2大环化合物分子识别的热力学性质510

6．1．3 结论510

6．1．3 Conclusions510

6．2 Thermodynamics of molecular recognition by macrocycles510

6．2．1 Thermodynamic origin of molecular recognition by cyclodextrin511

6．2．1环糊精分子识别的热力学起源511

6．2．2 卟啉分子识别的热力学起源573

6．2．2 Thermodynamic origin of molecular recognition by porphyrin573

6．2．3 Thermodynamic origin of molecular recognition by cyclophane and calixarene579

6．2．3 环番和杯芳烃分子识别的热力学起源579

6．3 结论583

6．3 Conclusions583

References585

参考文献585

Chapter 7 Determination of stability constants in supramolecular system597

第7章 超分子体系的稳定常数测定597

7．1．2 量热数据的处理和计算方法598

7．1．1基本原理598

7．1量热滴定法598

7．1．2 Data analysis and calculation method for calorimetry598

7．1．1 General principle598

7．1 Calorimetry598

7．2 Extraction Techniques604

7．2．1 Solvent extraction of metal ions and organic cations with electrically neutral extractants604

7．2．1电中性萃取剂对金属离子及有机离子的溶剂萃取604

7．2溶剂萃取法604

7．2．2 Solvent extraction of metal ions with proton-dissociable extractants609

7．2．2可质子化萃取剂对金属离子的溶剂萃取609

7．3．1 Determination of stoichiometric quality613

7．3 Spectroscopic methods613

7．3 光谱滴定法613

7．3．1化学计量比的确定613

7．3．2 Measurement of complex stability constant by spectroscopic titration616

7．3．2 光谱滴定法测定配合物稳定常数616

7．3．3 Measurement of complex stability constant by competitive inclusion620

7．3．3竞争包结法测定超分子配合物的稳定常数620

References621

参考文献621

Concluding remarks624

结束语624